Titolo | Solvent-free, PYR1ATFSI ionic liquid-based ternary polymer electrolyte systems. I. Electrochemical characterization |
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Tipo di pubblicazione | Articolo su Rivista peer-reviewed |
Anno di Pubblicazione | 2007 |
Autori | Kim, G.-T., Appetecchi Giovanni Battista, Alessandrini F., and Passerini S. |
Rivista | Journal of Power Sources |
Volume | 171 |
Paginazione | 861-869 |
ISSN | 03787753 |
Parole chiave | Chain length, Interfaces (materials), Interfacial resistance, Ionic conductivity, Ionic liquids, Polyelectrolytes, Solid polymer electrolytes (SPE), Ternary polymer electrolyte systems, Ternary systems |
Abstract | The electrical properties of solvent-free, PEO-LiTFSI solid polymer electrolytes (SPEs), incorporating different N-alkyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide, PYR1ATFSI, ionic liquids (ILs), are reported. For this purpose, PYR1ATFSI materials containing side alkyl groups with different chain-length and branching, i.e., n-propyl, sec-propyl, n-butyl, iso-butyl, sec-butyl and n-pentyl, were properly synthesized and homogeneously incorporated into the SPE samples without phase separation. The addition of ILs to PEO-LiTFSI electrolytes results in a large increase of the conductivity and in a decrease of the interfacial resistance with the lithium metal anode. Most of the PEO-LiTFSI-PYR1ATFSI samples showed similar ionic conductivities (>10-4 S cm-1 at 20 °C) and stable interfacial resistance values (400 Ω cm2 at 40 °C and 3000 Ω cm2 at 20 °C) upon several months of storage. Preliminary battery tests have shown that Li/P(EO)10LiTFSI + 0.96 PYR1ATFSI/LiFePO4 solid-state cells are capable to deliver a capacity of 125 mAh g-1 and 100 mAh g-1 at 30 °C and 25 °C, respectively. © 2007 Elsevier B.V. All rights reserved. |
Note | cited By 86 |
URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-34548498410&doi=10.1016%2fj.jpowsour.2007.07.020&partnerID=40&md5=e0837215927bd0ab75658bb3e6d4ec88 |
DOI | 10.1016/j.jpowsour.2007.07.020 |
Citation Key | Kim2007861 |