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Mixtures of ionic liquids for low temperature electrolytes

TitoloMixtures of ionic liquids for low temperature electrolytes
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2012
AutoriKunze, M., Jeong S., Appetecchi Giovanni Battista, Schönhoff M., Winter M., and Passerini S.
RivistaElectrochimica Acta
Volume82
Paginazione69-74
ISSN00134686
Parole chiaveBinary mixtures, Bis(trifluoromethane sulfonyl)imide, diffusion, Electric conductivity, Electrolytes, Electrolytic capacitors, Four-order, Ionic liquids, Lithium battery system, Low temperatures, PFG-NMR, Pyrrolidinium, Self-diffusion coefficients, Super capacitor
Abstract

The conductivity, viscosity and the self-diffusion coefficient of pyrrolidinium-based ILs (ILs), N-butyl-N-methyl pyrrolidinium- bis(trifluoromethanesulfonyl)imide (Pyr 14TFSI) and N-methyl-N-propyl pyrrolidinium-bis(fluorosulfonyl)imide (Pyr 13FSI), and their binary mixtures were investigated in order to better understand their behavior as electrolyte components in supercapacitor and lithium battery systems. The IL mixtures showed excellent low temperature properties far exceeding those of the pure IL materials. For example, at -40°C the conductivity of binary mixtures was found to be up to four orders of magnitude higher than that of the pure ILs. © 2012 Elsevier Ltd.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84866381189&doi=10.1016%2fj.electacta.2012.02.035&partnerID=40&md5=3e168b3149a5ef57aa504bb6ba8e93e2
DOI10.1016/j.electacta.2012.02.035
Citation KeyKunze201269