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NMR investigation of ionic liquid-LiX mixtures: Pyrrolidinium cations and TFSI anions

TitoloNMR investigation of ionic liquid-LiX mixtures: Pyrrolidinium cations and TFSI anions
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2005
AutoriNicotera, I., Oliviero C., Henderson W.A., Appetecchi Giovanni Battista, and Passerini S.
RivistaJournal of Physical Chemistry B
Volume109
Paginazione22814-22819
ISSN15206106
Parole chiaveBinary mixtures, Electrochemistry, Ionic liquids, Lithium compounds, Lithium salt, Negative ions, Nuclear magnetic resonance spectroscopy, organic compounds, Positive ions, Room-temperature
Abstract

In this paper is reported an extensive NMR characterization of N-methyl-N-propyl-pyrrolidinium bis-(trifluoromethanesulfonyl)imide (PYR 13TFSI) room-temperature ionic liquid and its mixtures with LiTFSI. NMR was used to investigate the interactions between the ionic liquid and lithium salt and the diffusion coefficients of all ionic species present in these mixtures. The results are compared with previous DSC, Raman, and electrochemical investigations. © 2005 American Chemical-Society.

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cited By 108

URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-29444442081&doi=10.1021%2fjp053799f&partnerID=40&md5=a6a6e9fdc79dd6784c62099c361ce68d
DOI10.1021/jp053799f
Citation KeyNicotera200522814