| Title | Rationalization of hydrogen production by bulk g-C3N4: an in-depth correlation between physico-chemical parameters and solar light photocatalysis |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 2018 |
| Authors | Speltini, A., Pisanu A., Profumo A., Milanese C., Sangaletti L., Drera G., Patrini M., Pentimalli Marzia, and Malavasi L. |
| Journal | RSC Advances |
| Volume | 8 |
| Pagination | 39421-39431 |
| ISSN | 20462069 |
| Keywords | Batch-to-batch reproducibility, Diffuse reflectance spectroscopy, Gas adsorption, High-resolution scanning electron microscopies, Hydrogen production, light, Light absorption, metabolism, Nitrogen adsorption measurements, Optical properties, Photocatalysis, Photocatalytic activities, Physico - chemical parameters, polymerization, Polymerization temperature, Scanning electron microscopy, Solar power generation, Structural and optical properties, Thermogravimetric analysis, Triethanolamine, Urea, X ray photoelectron spectroscopy |
| Abstract | {The aim of this work is the systematic study of the photocatalytic activity of bulk graphitic carbon nitride (g-C3N4) in relation with the physical-chemical, structural and optical properties of the semiconductor. Fourteen g-C3N4 samples have been prepared by thermal condensation starting from three different precursor (melamine, dicyandiamide and urea) and exploring various temperatures (in the range 500-700 °C). The materials obtained have been deeply characterized by high resolution scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, nitrogen adsorption measurements (BET method), X-ray photoelectron spectroscopy and diffuse reflectance spectroscopy. Each semiconductor, coupled with Pt co-catalyst, was tested for hydrogen gas production from aqueous triethanolamine as model sacrificial agent, under simulated solar light. The hydrogen evolution profiles turned out to be strictly dependent on precursor type and synthesis temperature, with the highest evolution rate observed for the samples series produced from urea (up to ca. 4400 μmol g−1 h−1). The results, corroborated by the excellent inter-day precision of irradiation tests (RSD < 5% |
| Notes | cited By 4 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85057764093&doi=10.1039%2fc8ra08880b&partnerID=40&md5=341cf5049358c7054457a526e9db618d |
| DOI | 10.1039/c8ra08880b |
| Citation Key | Speltini201839421 |
