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Metal distribution in sediments from the Adriatic Sea

TitleMetal distribution in sediments from the Adriatic Sea
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2010
AuthorsCalace, N., Cardellicchio N., Petronio B.M., Pietrantonio Massimiliana, and Pietroletti M.
JournalToxicological and Environmental Chemistry
Volume92
Pagination1065-1081
ISSN02772248
KeywordsAdriatic Sea, Biogeochemistry, Biological materials, Chemical forms, Chemical speciation, concentration (composition), Copper and zinc, element mobility, heavy metal, Italy, Lead, Manganese, Manganese compounds, marine sediment, Marine sediments, Mediterranean Sea, Metal concentrations, Metal distributions, Metal levels, Metal speciation, Metals, Nickel alloys, organic compounds, organic matter, Po River, sediment pollution, Sedimentology, speciation (chemistry), Study areas, Submarine geology, sulfide, Water circulation, Zinc, Zinc sulfide
Abstract

Total metal concentrations (Cu, Ni, Pb, Zn, Fe, and Mn) and their distribution in different chemical forms (speciation) were determined in sediments from the Adriatic Sea in order to evaluate contamination and mobility of metals. The study was carried out on marine sediments collected in two areas of the Adriatic Sea differently influenced by Po river waters. Metal distribution in the study area depends prevalently on water circulation and on organic matter distribution. Among metal levels, significant correlations between copper and zinc and between lead and nickel were found, suggesting common and specific sources. As regards metal speciation, the distribution of different chemical forms changes with the metal. The prevailing zinc phases, for example mobile forms, and sulphide together are greater than 50% of total metal. Nickel is mainly present in sediments as sulphide, and the preferential association of copper with organic matter is evident. Lead and manganese are preferentially found as mobile forms (more of 30% for lead, 40% or more for manganese). © 2010 Taylor & Francis.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-77953093527&doi=10.1080%2f02772240903120982&partnerID=40&md5=87c21125a243c9d1a9b7d271a5bee50a
DOI10.1080/02772240903120982
Citation KeyCalace20101065