| Title | Ionic liquid electrolytes for safer lithium batteries: I. Investigation around optimal formulation |
|---|---|
| Publication Type | Presentazione a Congresso |
| Year of Publication | 2016 |
| Authors | Moreno, M., Simonetti E., Appetecchi Giovanni Battista, Carewska M., Montanino M., Kim G.-T., Loeffler N., and Passerini S. |
| Conference Name | ECS Transactions |
| Publisher | Electrochemical Society Inc. |
| ISBN Number | 9781607685395 |
| Keywords | Bis(fluorosulfonyl)imide, Bis(trifluoromethane sulfonyl)imide, carbon, Electric batteries, Electrochemical stabilities, Electrolytes, Ion-transport properties, Ionic liquid electrolytes, Ionic liquids, Ionic-liquid based electrolytes, Liquids, Lithium, Lithium batteries, Mixtures, Optimal formulation, Working electrode |
| Abstract | In this paper we report on the investigation of ionic liquid-based electrolytes with enhanced characteristics. In particular, we have studied ternary mixtures based on the lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt and two ionic liquids sharing the same cation (N-methyl-N-propyl pyrrolidinium, PYR13), but different anions, bis(trifluoromethanesulfonyl)imide (TFSI) and bis(fluorosulfonyl)imide (FSI). The LiTFSIPYR13TFSI-PYR13FSI mixtures exhibit better ion transport properties (about 10-3 S cm-1 at -20 °C) with respect to similar ionic liquid electrolytes till reported in literature. An electrochemical stability window of 5 V is observed in carbon working electrodes. © The Electrochemical Society. |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84990890550&doi=10.1149%2f07301.0067ecst&partnerID=40&md5=83f80aafd907950d8f7b278da6f4b463 |
| DOI | 10.1149/07301.0067ecst |
| Citation Key | Moreno201667 |
