Title | Electrochemical behaviour of a composite Rh/TiO 2 layer formed potentiodynamically on titanium surface |
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Publication Type | Articolo su Rivista peer-reviewed |
Year of Publication | 2006 |
Authors | Mentus, S., Krstić I., Tešić Ž., and Montone Amelia |
Journal | Materials Science Forum |
Volume | 518 |
Pagination | 265-270 |
ISBN Number | 9780878494057 |
ISSN | 02555476 |
Keywords | Deposition, Electrocatalysis, Hydrogen underpotential deposition, Oxygen reduction reaction, Reaction kinetics, Rhodium compounds, Rhodium electrodeposition, Scanning electron microscopy, Surface chemistry, Titanium surfaces |
Abstract | Potentiodynamic polarization of a mechanically polished titanium electrode in a diluted solution of Rhodium(III) chloride in 0.1 M perchloric acid was performed, resulting in simultaneous formation of both Rh and TiO 2 films. The morphology of obtained Rh/TiO 2 composite film followed the morphology of titanium support, as evidenced by SEM technique. This composite surface was examined by cyclic voltammetry in both acidic and alkaline solutions, in the potential region of both hydrogen and oxygen underpotential deposition. The charge related to hydrogen underpotential deposition corresponded to a surface roughness of 43. As a consequence of high surface roughness, the diffusion current of oxygen reduction in an oxygen saturated 0.1 M NaOH solution, measured by voltammetry on rotating disc electrode, was found to be comparable to the current of hydrogen underpotential deposition. |
Notes | cited By 0; Conference of 7th Conference of the Yugoslav Materials Research Society - Recent Developments in Advanced Materials and Processes, YUCOMAT VII ; Conference Date: 12 September 2005 Through 16 September 2005; Conference Code:70887 |
URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-37849052187&partnerID=40&md5=bfd4c350f5aa772c8aa6bb154ca5ace8 |
Citation Key | Mentus2006265 |