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Lattice and ion dynamics in gel electrolytes based on poly(acrylonitrile) by6Li-7Li NMR

TitleLattice and ion dynamics in gel electrolytes based on poly(acrylonitrile) by6Li-7Li NMR
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication1995
AuthorsMustarelli, P., Tomasi C., Villa M., Appetecchi Giovanni Battista, and Croce F.
JournalIonics
Volume1
Pagination147-152
ISSN09477047
Abstract

Two composite gel electrolytes prepared from mixtures of poly(acrylonitrile) (PAN), propylene carbonate (PC), ethylene carbonate (EC) and LiClO4 have been studied with differential scanning calorimetry (DSC) and7Li-6Li NMR. The data allow estimation of ionic conductivities, local (short range) diffusivities, and lattice dynamics. Furthermore, they point to an unexpected behavior of the Li-rich sample that hints to a complex LiClO4-PAN phase diagram. © 1995 IfI - Institute for Ionics.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-51249161235&doi=10.1007%2fBF02388673&partnerID=40&md5=6bcab26c995d7b35d482f31ea806ac92
DOI10.1007/BF02388673
Citation KeyMustarelli1995147