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Poly (ethylene oxide)-LiN(SO2CF2CF3)2 polymer electrolytes II. Characterization of the interface with lithium

TitlePoly (ethylene oxide)-LiN(SO2CF2CF3)2 polymer electrolytes II. Characterization of the interface with lithium
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2002
AuthorsAppetecchi, Giovanni Battista, and Passerini S.
JournalJournal of the Electrochemical Society
Volume149
PaginationA891-A897
ISSN00134651
KeywordsCharacterization, Differential scanning calorimetry, Interfaces (materials), Lithium compounds, Lithium foil electrodes, Polyelectrolytes, Polyethylene oxides, X ray diffraction analysis
Abstract

An analysis of the interface developed between lithium metal and poly(ethylene oxide) (PEO)-lithium bis(perfluoroethysulfonyl)imide (LiBETI) electrolytes was studied. The studies were performed as a function of polymer electrolyte salt concentration and temperature both in rest and in kinetic conditions by means of impedance measurements and galvanostatic tests, respectively. The results showed that low salt concentration P(EO)nLiBETI polymer electrolytes are good candidates for lithium-dry polymer batteries operating at medium-high temperature (60-90 °C).

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0036642108&doi=10.1149%2f1.1483098&partnerID=40&md5=8751e67c8a1fa6524ab4d10832a02ff9
DOI10.1149/1.1483098
Citation KeyAppetecchi2002