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PEO-based electrolyte membranes based on LiBC4O8 salt

TitlePEO-based electrolyte membranes based on LiBC4O8 salt
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2004
AuthorsAppetecchi, Giovanni Battista, Zane D., and Scrosati B.
JournalJournal of the Electrochemical Society
Volume151
PaginationA1369-A1374
ISSN00134651
KeywordsBall milling, Differential scanning calorimetry, Electrochemistry, Electrolyte membranes, Electrolytes, Hot pressing, Impedance spectroscopy, Ion transfer, Ionic conduction, Lithium batteries, Plasticizers, Polyethylene oxides, Polymer electrolytes, Polymeric membranes, Polymethyl methacrylates, Thermodynamic stability, X ray diffraction
Abstract

New types of solvent-free, lithium-conducting polymer electrolytes have been prepared by hot-pressing a blend of poly(ethylene oxide) (PEO) and a lithium bis(oxalato)borate, LiBC4O8 (LiBOB) salt. The membranes have been characterized in terms of ionic conductivity and lithium ion transference number. In addition, the thermal and the structural properties were investigated by differential scanning calorimetry and X-ray diffraction. The results show that the PEO-LiBOB membranes have a high ionic conductivity even at low-medium temperatures. © 2004 The Electrochemical Society. All rights reserved.

Notes

cited By 40

URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-4944242235&doi=10.1149%2f1.1774488&partnerID=40&md5=09d452c286d042e939a4c371caa4c468
DOI10.1149/1.1774488
Citation KeyAppetecchi2004