| Title | Investigation of the electrochemical properties of polymer-LiX-ionic liquid ternary systems |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 2007 |
| Authors | Tizzani, C., Appetecchi Giovanni Battista, Carewska M., Kim G.-T., and Passerini S. |
| Journal | Australian Journal of Chemistry |
| Volume | 60 |
| Pagination | 47-50 |
| ISSN | 00049425 |
| Keywords | Amines, Electrochemical devices, Electrochemistry, Electrolytes, Fluorinated polymers, Ionic conduction, Ionic liquids, Negative ions, Polytetrafluoroethylenes, Surface chemistry, Ternary systems |
| Abstract | The electrochemical properties of ternary systems that consist of a polymer, a lithium salt, and an ionic liquid that shares the same anion (TFSI, bis(trifluoromethansulfonyl)imide) are reported and compared. The investigation involved two different polymers (PVdF-HFP and PTFE) that were selected because of their common use in lithium-based electrochemical devices. It was found that PVdF-HFP swelled by the ionic liquid used in the work while porous PTFE remained inert. The ternary electrolytes showed interesting ionic conductivities. However, the presence of fluorinated polymers resulted in poor interfacial properties with lithium metal electrodes. © CSIRO 2007. |
| Notes | cited By 14 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-33846582414&doi=10.1071%2fCH06293&partnerID=40&md5=7b73d70df16b79e71dad4973fd15578b |
| DOI | 10.1071/CH06293 |
| Citation Key | Tizzani200747 |
