Title | Nanoscale organization in piperidinium-based room temperature ionic liquids |
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Publication Type | Articolo su Rivista peer-reviewed |
Year of Publication | 2009 |
Authors | Triolo, A., Russina O., Fazio B., Appetecchi Giovanni Battista, Carewska M., and Passerini S. |
Journal | Journal of Chemical Physics |
Volume | 130 |
ISSN | 00219606 |
Keywords | Alkyl chains, Alkylation, Bis(trifluoromethane sulfonyl)imide, Complex natures, Ionic liquids, Ionization of liquids, Ions, Molten state, Nano-scale organizations, Phase diagrams, Polar regions, Room-temperature ionic liquids, Structural orders, Wide angle x-ray scatterings |
Abstract | Here we report on the complex nature of the phase diagram of N -alkyl- N -methylpiperidinium bis(trifluoromethanesulfonyl)imide ionic liquids using several complementary techniques and on their structural order in the molten state using small-wide angle x-ray scattering. The latter study indicates that the piperidinium aliphatic alkyl chains tend to aggregate, forming alkyl domains embedded into polar regions, similar to what we recently highlighted in the case of other ionic liquids. © 2009 American Institute of Physics. |
Notes | cited By 132 |
URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-65149091818&doi=10.1063%2f1.3119977&partnerID=40&md5=6e463424edafa033212a75a07c170aaf |
DOI | 10.1063/1.3119977 |
Citation Key | Triolo2009 |