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Anelasticity in nanostructured MgH2-Mg: Correlation with hydrogen sorption kinetics

TitoloAnelasticity in nanostructured MgH2-Mg: Correlation with hydrogen sorption kinetics
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2009
AutoriPasquini, L., Amadori S., Bonetti E., Callini E., Fiorini A.L., Montone Amelia, and M. Antisari Vittori
RivistaMaterials Science and Engineering A
Volume521-522
Paginazione151-154
ISSN09215093
Parole chiaveActivation energy, Anelasticity, Ball milling, Desorption, Differential scanning calorimetry, High vacuum, Hydrogen, Hydrogen desorption, Hydrogen sorption, Hydrogen storage, Internal friction peak, Magnesium, Magnesium hydride, Mechanical spectroscopy, Nano-structured, Nanostructured magnesium, Nanostructures, Resonance, Resonance frequencies, Self-Diffusion
Abstract

Mechanical spectroscopy is employed, in correlation with differential scanning calorimetry and hydrogen sorption analysis, to investigate the hydrogen desorption reaction in nanostructured magnesium hydride prepared by ball milling. The hydrogen desorption process is marked by a dramatic drop of the specimen's resonance frequency and by an internal friction peak that occurs - under high vacuum - at about 580 K. After full hydrogen desorption, a broad anelastic relaxation peak similar to commercial Mg is observed at 470 K, with activation energy close to the one for self-diffusion in Mg. © 2009 Elsevier B.V. All rights reserved.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-68949096366&doi=10.1016%2fj.msea.2008.09.114&partnerID=40&md5=ffe2afbf6713dfc64e05d29a6a885f4a
DOI10.1016/j.msea.2008.09.114
Citation KeyPasquini2009151