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Mechanochemical exfoliation of graphite and its polyvinyl alcohol nanocomposites with enhanced barrier properties

TitleMechanochemical exfoliation of graphite and its polyvinyl alcohol nanocomposites with enhanced barrier properties
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2009
AuthorsBorriello, Carmela, De Maria A., Jović N., Montone Amelia, Schwarz M., and Antisari M.V.
JournalMaterials and Manufacturing Processes
Volume24
Pagination1053-1057
ISSN10426914
KeywordsBarrier properties, Graphite, Graphite nano-sheets, Graphite powder, Graphite sheets, Homopolymers, Low energies, Mechanical methods, Mechanochemicals, Nanocomposites, Polymeric matrices, Water vapor, Water vapor permeability
Abstract

Polyvinylalcohol/graphite nanocomposites with graphite nanosheets have been prepared by a mechanical method based on grinding of graphite powder, under low energy pure shearing milling, using water or KOH as lubricant. The use of different lubricant concurs to obtain graphite sheets that differently disperse in hydrophilic polymeric matrix. An improvement of water vapor permeability (up to 12%), compared with homopolymer, has been observed.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-77949546021&doi=10.1080%2f10426910903022346&partnerID=40&md5=6fd2fca1bd80371ff0216f1874adccf5
DOI10.1080/10426910903022346
Citation KeyBorriello20091053